Oblon, Spivak, McClelland, Maier & Neustadt
Crosslinked polyester for toner and process for preparation thereof
 Disclosed is a crosslinked polyester for a toner, which has an acid value of 5 to 20 mgKOH/g, a flow index of 0.1.times.10.sup.-4 to 300.times.10.sup.-4 ml/sec and a softening point lower than 145.degree. C., the polyester being formed by mixing a dicarboxylic acid component, a diol component and at least one crosslinking component selected from a polyfunctional carboxylic acid component having a trivalency or a higher valency and a polyhydric alcohol component having a trivalency or a higher valency at a mixing ratio represented by the following formula (1), reacting the mixture at a reaction ratio represented by the following formula (2) and subjecting the esterification product to polycondensation and crosslinking. EQU 0.8.ltoreq.R.ltoreq.1+5a (1) EQU 0.7.ltoreq.P.ltoreq.[R/(1+a)].sup.1/2 (2) wherein R is the ratio of the mole number of the total alcohol components to the mole number of the total acid components, a is the ratio of the sum of the mole number of the polyvalent carboxylic acid component and the mole number of the polyhydric alcohol component to the mole number of the total acid components, and P is the conversion of the carboxylic acid components. The toner comprising this crosslinked polyester as the binder has an excellent offset-preventing property, low-temperature fixing property and blocking resistance and good charging characteristics with a high moisture resistance, and gives a copied image having good sharpness and image density. 
Mitsubishi Rayon Company, Ltd.
G G C
G03G G03G C08G
inventional inventional inventional
Hirokazu Shinji Masayuki Ryo Noriyuki
Ito Kubo Takyu Funato Tajiri